Scott Guthries has a free 185 page book chapter on ASP.NET MVC that you can download for free. Info on the book can be found at : http://tinyurl.com/aspnetmvc

The chapter is available directly at : http://aspnetmvcbook.s3.amazonaws.com/aspnetmvc-nerdinner_v1.pdf

This pdf is great as it builds an application from scratch and introduces all of the concepts involved with ASP.NET MVC along the way.

I encourage you to check it out...